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2021犟新蟲 (小有名氣)
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[求助]
求Mn-MOF模擬衍射數(shù)據(jù) 已有2人參與
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這個(gè)文獻(xiàn)也沒(méi)有寫清該MOF的具體名稱,很困惑,急需這個(gè)結(jié)構(gòu)的模擬數(shù)據(jù)或CIF文件,圖中給了相應(yīng)的結(jié)構(gòu),但自己又不會(huì)做 文章鏈接:https://doi.org/10.1021/acsami.4c05031 @jackdeng @lich666 發(fā)自小木蟲Android客戶端 |
專家顧問(wèn) (文壇精英)
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專家經(jīng)驗(yàn): +1066 |
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我覺(jué)得你沒(méi)有認(rèn)真看這個(gè)文獻(xiàn),實(shí)驗(yàn)部分 2.2. Preparation of Mn-MOF Nanowire Paper A hydrothermal method was used for the synthesis of the Mn-MOF nanowires. (38−41) Nitrilotriacetic acid (NTA, 3 mmol) and isopropyl alcohol (10 mL) were added to an aqueous solution (30 mL) of MnCl2 (6 mmol). The mixture solution was magnetically stirred and then transferred into Teflon-lined stainless-steel autoclaves, followed by heating at 180 °C for 6 h. After cooling to room temperature, the product was washed with deionized water. 可以看出,依照參考文獻(xiàn)38-41合成的Mn-MOF,其中文獻(xiàn)38是 Matter 6, 3598–3607,這個(gè)文獻(xiàn)里合成了一個(gè)Mn-MOF,所用方法和原料與你給的文獻(xiàn)是一樣的, Material Syntheses In a typical synthesis, 6 mmol MCl2 (i.e., 6 mmol CoCl2 for Co-NTA, 6 mmol FeCl2 for FeNTA, 6 mmol MnCl2 for Mn-NTA, 3 mmol FeCl2 + 3 mmol CoCl2 for FeCo-NTA, 3 mmol FeCl2 + 3 mmol MnCl2 for FeMn-NTA, 3 mmol CoCl2 + 3 mmol MnCl2 for CoMn-NTA, or 2 mmol CoCl2 + 2 mmol FeCl2 + 2 mmol MnCl2 for CoFeMn-NTA) was dissolved into 30 mL deionized water, and then 0.6 g (3 mmol) nitrilotriacetic acid (H3NTA) and 10 mL 2-propanol were added into the above solution. The mixture solution was later transferred into a Teflon-lined stainless-steel autoclave for solvothermal reaction. After heating for 6 h at 180 oC, the M-NTA nanowire products were obtained by washing with deionized water and filtering. 這個(gè)文獻(xiàn)里提到了一個(gè)晶體結(jié)構(gòu),對(duì)應(yīng)的CCDC: 1554264 鏈接: https://pan.baidu.com/s/1CM2MYPRlCEg6Fl_2mx2KiA?pwd=q5kr 提取碼: q5kr |

木蟲 (正式寫手)
木蟲 (正式寫手)
新蟲 (小有名氣)
送紅花一朵 |
首先感謝您的回復(fù),但1554264實(shí)際上是Co-MOF的CIF的文件他的附件確實(shí)有一些Mn-MOF的參數(shù),但是自己對(duì)這個(gè)所知甚少,還請(qǐng)不吝賜教 發(fā)自小木蟲Android客戶端 |
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