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no-name鐵桿木蟲 (著名寫手)
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[求助]
如何從CV中計算氧化還原峰加權(quán)中心電位weighted center position of redox peaks
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如何從CV圖中計算得到氧化還原峰的加權(quán)中心電位（the weighted center position of redox peaks）？ 如圖，圖中文字對這個所謂的加權(quán)中心電位進行了解釋，但不明白具體是如何計算的？能用origin完成計算過程嗎？怎么實現(xiàn)？ 萬望大家解疑釋惑，感謝！ "The red regions and the red dash line represent the calculation method for the redox weighted centers. First, the linear double-layer-capacitance background corrections were applied to extract the oxidation and reduction peaks, respectively. Second, function Vweighted = ∫VdQ/∫dQ was applied on the corrected oxidation and reduction peaks to calculate the oxidation and reduction weighted centers, where Q is the corresponding charge transfer at the voltage V in the redox process. At last, the average value of the oxidation and reduction weighted centers was used as the redox weighted center, which is the red dash line shown in the figure." Graphical representation of the calculations of the weighted center.png |
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