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These deuterodimers indicate the sense and magnitude of olefin facial selectivity for insertions into the metal-n-pentyl bond with the chiral 1-pentene providing the probe of the absolute stereochemistry for additions to olefin double bonds |
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These deuterodimers indicate the sense and magnitude of olefin facial selectivity for insertions into the metal-n-pentyl bond with the chiral 1-pentene providing the probe of the absolute stereochemistry for additions to olefin double bonds 這類氘代二聚體體現(xiàn)了烯烴正面選擇性插入正戊基金屬基團(tuán)與手性1-戊烯的鍵合程度及其意義,并為添加入烯烴雙鍵提供了絕對(duì)立體化學(xué)結(jié)構(gòu)的探針。 |
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