| 5 | 1/1 | 返回列表 |
| 查看: 1716 | 回復(fù): 6 | ||||
| 【懸賞金幣】回答本帖問題,作者2021犟將贈送您 150 個金幣 | ||||
| 當(dāng)前只顯示滿足指定條件的回帖,點擊這里查看本話題的所有回帖 | ||||
2021犟新蟲 (小有名氣)
|
[求助]
求Mn-MOF模擬衍射數(shù)據(jù) 已有2人參與
|
|||
|
這個文獻也沒有寫清該MOF的具體名稱,很困惑,急需這個結(jié)構(gòu)的模擬數(shù)據(jù)或CIF文件,圖中給了相應(yīng)的結(jié)構(gòu),但自己又不會做 文章鏈接:https://doi.org/10.1021/acsami.4c05031 @jackdeng @lich666 發(fā)自小木蟲Android客戶端 |
專家顧問 (文壇精英)
![]() |
專家經(jīng)驗: +1066 |
|
Matter 6, 3598–3607文中提到, Moreover, the PXRD patterns (Figure 2C) and ultralong nanowire morphology (Figures S4–S8) of other members, i.e., Fe-NTA, Mn-NTA, and binary M-NTA, are almost identical to those of Co-NTA, suggesting that they are all isostructural. isostructural表示這幾個化合物是同構(gòu)的,就是把Co換成Mn,F(xiàn)e不會改變化合物的配位方式和空間排列方式,所以用Co的單晶數(shù)據(jù)去模擬pxrd譜圖可以用來與Mn的材料比對,沒什么問題 |

木蟲 (正式寫手)
木蟲 (正式寫手)
專家顧問 (文壇精英)
![]() |
專家經(jīng)驗: +1066 |
|
我覺得你沒有認(rèn)真看這個文獻,實驗部分 2.2. Preparation of Mn-MOF Nanowire Paper A hydrothermal method was used for the synthesis of the Mn-MOF nanowires. (38−41) Nitrilotriacetic acid (NTA, 3 mmol) and isopropyl alcohol (10 mL) were added to an aqueous solution (30 mL) of MnCl2 (6 mmol). The mixture solution was magnetically stirred and then transferred into Teflon-lined stainless-steel autoclaves, followed by heating at 180 °C for 6 h. After cooling to room temperature, the product was washed with deionized water. 可以看出,依照參考文獻38-41合成的Mn-MOF,其中文獻38是 Matter 6, 3598–3607,這個文獻里合成了一個Mn-MOF,所用方法和原料與你給的文獻是一樣的, Material Syntheses In a typical synthesis, 6 mmol MCl2 (i.e., 6 mmol CoCl2 for Co-NTA, 6 mmol FeCl2 for FeNTA, 6 mmol MnCl2 for Mn-NTA, 3 mmol FeCl2 + 3 mmol CoCl2 for FeCo-NTA, 3 mmol FeCl2 + 3 mmol MnCl2 for FeMn-NTA, 3 mmol CoCl2 + 3 mmol MnCl2 for CoMn-NTA, or 2 mmol CoCl2 + 2 mmol FeCl2 + 2 mmol MnCl2 for CoFeMn-NTA) was dissolved into 30 mL deionized water, and then 0.6 g (3 mmol) nitrilotriacetic acid (H3NTA) and 10 mL 2-propanol were added into the above solution. The mixture solution was later transferred into a Teflon-lined stainless-steel autoclave for solvothermal reaction. After heating for 6 h at 180 oC, the M-NTA nanowire products were obtained by washing with deionized water and filtering. 這個文獻里提到了一個晶體結(jié)構(gòu),對應(yīng)的CCDC: 1554264 鏈接: https://pan.baidu.com/s/1CM2MYPRlCEg6Fl_2mx2KiA?pwd=q5kr 提取碼: q5kr |

| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 化學(xué) 0703求調(diào)劑 總分293 一志愿211 +8 | 土土小蟲 2026-03-03 | 8/400 |
|
|---|---|---|---|---|
|
[考研] 一志愿武漢理工大學(xué)-085602-總分296分-求調(diào)劑 +4 | 紫川葡柚 2026-03-04 | 4/200 |
|
|
[考研] 材料085600 303求調(diào)劑 +5 | 1bygone 2026-03-04 | 5/250 |
|
|
[考研]
|
15779376950 2026-03-01 | 8/400 |
|
|
[考研] 301求調(diào)劑 +3 | 李LJR 2026-03-04 | 3/150 |
|
|
[考研] 材料與化工,291分,求調(diào)劑 +5 | 咕嚕咕嚕123123 2026-03-04 | 5/250 |
|
|
[考研] 325求調(diào)劑 +5 | 學(xué)家科 2026-03-04 | 5/250 |
|
|
[考研]
|
旅行中的紫葡萄 2026-03-03 | 4/200 |
|
|
[考研] 306求調(diào)劑 +7 | 張張張張oo 2026-03-03 | 7/350 |
|
|
[考研] 278求調(diào)劑 +3 | 滿天星11_22 2026-03-02 | 3/150 |
|
|
[考研] 268求調(diào)劑 +6 | 好運連綿不絕 2026-03-02 | 6/300 |
|
|
[考研] 291求調(diào)劑 +3 | MuoLuo1312 2026-03-02 | 6/300 |
|
|
[考研] 沒上岸的看過來 +3 | tangxiaotian 2026-03-01 | 3/150 |
|
|
[考研] 課題組接收材料類調(diào)劑研究生 +6 | gaoxiaoniuma 2026-02-28 | 9/450 |
|
|
[考研] 324求調(diào)劑 +4 | wxz2 2026-03-03 | 5/250 |
|
|
[考研] 307求調(diào)劑 +6 | wyyyqx 2026-03-01 | 6/300 |
|
|
[考研] 298求調(diào)劑 +10 | 人間唯你是清歡 2026-02-28 | 14/700 |
|
|
[考研] 291 求調(diào)劑 +3 | 化工2026屆畢業(yè)?/a> 2026-03-02 | 3/150 |
|
|
[考研] 化工專碩342,一志愿大連理工大學(xué),求調(diào)劑 +6 | kyf化工 2026-02-28 | 7/350 |
|
|
[考研] 275求調(diào)劑 +3 | L-xin? 2026-03-01 | 6/300 |
|