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催化劑催化銀蟲 (小有名氣)
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[求助]
uio-66-nh2晶體如何養(yǎng) 已有2人參與
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請教如何能養(yǎng)出uio-66-nh2的晶體 @bionics @流浪南昌 @初次見面 發(fā)自小木蟲Android客戶端 |
銀蟲 (小有名氣)
送紅花一朵 |
謝謝你大佬,我還有個(gè)問題就是我用2氨基對苯二甲酸98%(麥克林)和98%的ZrCl4(麥克林)合出來的并不是文獻(xiàn)中說的黃色,而是紅色的,這是我藥品的顏色嗎求指教 發(fā)自小木蟲Android客戶端 |
專家顧問 (文壇精英)
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專家經(jīng)驗(yàn): +1066 |
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早就有文獻(xiàn)報(bào)道了 A new synthesis was developed for making large single crystals of UiO-66. It uses a combination of N,N-diethylformamide (DEF) and formic acid. A ratio of 1:1 by volume produces the largest crystals (Figure 2). The starting materials of ZrOCl2⋅8 H2O (0.037 mmol) and H2BDC (0.03 mmol) were dissolved in DEF prior to mixing and addition of formic acid. The resulting solution was placed in an oven for 2 days at 408 K. Furthermore, it was found that these conditions could be extended to a variety of zirconium salts and functionalized linkers. This includes ZrCl4, ZrBr4, Zr(OPr)4, H2BDC-Br, H2BDC-NH2, H2BDC-NO2, and H2BDC-Me2, thus demonstrating the versatility of these synthetic conditions (see the Supporting Information for further details). https://onlinelibrary.wiley.com/doi/10.1002/anie.201505461 |

新蟲 (初入文壇)
新蟲 (初入文壇)
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